Inorganic Chemistry, Vol.46, No.8, 2956-2958, 2007
Novel 3D Ln(III)-Cu-I supramolecular architecture based on 2D MOFs with (6,3) topology
Three novel coordination polymers, [LnCu(PZDC)(3)]center dot[Ln(H2O)(9)](0.5)center dot[(H2O)(7)H+](0.5) [Ln = La (1), Eu (2), Gd (3)], were synthesized. They are the first 3d-4f heterometallic framework with supramolecular 1D channels, in which lanthanide hydrate cations and lattice water molecules are located.