The electrosynthesis of polyaniline on the bare aluminum and pre-treated aluminum surface achieved in aqueous H2PtCl6 solution saturated with NaF for few seconds is described. The effect of some factors such as pre-treatment time, aniline and sulfuric acid concentrations on the electropolymerization process was investigated and optimum conditions were obtained. The stability of polyaniline film on the pre-treated aluminum electrode (Al-Pt) was studied as function of the potential imposed on the electrode. For applied electrode potentials of 0.1-0.7 V, the first-order degradation rate constant, k, of polyaniline film varies between 1 x 10(-6) and 2 x 10(-5) s(-1), and a relatively low slope (i.e. 2.1) was obtained for the plot of log k versus E. The coatings were characterized by scanning electron microscopy (SEM), and cyclic voltammetric behavior of the polyaniline-deposited Al electrode (Al/PANI) and polyaniline-deposited Al-Pt electrode (Al-Pt/PANI) in 0.1 H2SO4 solutions is described. The electrocatalytic activity of the Al-Pt/PANI electrode against para-benzoquinone/hydroquinone (Q/H(2)Q) and Fe(CN)(6)(3-)/Fe(CN)(6)(4-) redox systems was investigated and the obtained results are compared with those obtained on Al/PANI and bulk Pt electrodes. (c) 2006 Elsevier Ltd. All rights reserved.