열분해 잔유를 원료로 한 분산제의 제조 및 특성

최상원; 김은영; 장우석; 김빅토르; 문장수; Sang-Won Choi; Eun-Young Kim; Woo-Seok Chang; Viktor Kim; Jang-Soo Moon

Journal of the Korean Industrial and Engineering Chemistry, Vol.18, No.5, 490-494, October, 2007

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열분해 잔유를 원료로 한 분산제의 제조 및 특성

The Preparation and Properties of Petroleum Sulfonate Dispersant

최상원^†, 김은영, 장우석, 김빅토르, 문장수¹

전남대학교 공학대학 화학시스템 공학 전공
¹한국환경기술진흥원

Sang-Won Choi^†, Eun-Young Kim, Woo-Seok Chang, Viktor Kim, and Jang-Soo Moon¹

Department of Chemical System Engineering, Chonnam National University, Yeosu 550-749, Korea
¹KIEST, Seoul 122-706, Korea

E-mail:

초록

올레핀 제조를 위한 열분해공정에서의 잔유(PPRO)를 원료로 황산화 반응을 통하여, polynaphthalene sulfonate formaldehyde condensate (PNS) 반응 공정에 비하여 좀더 단순한 공정으로 2 h 이내의 반응시간에도 우수한 성능의 무기물 분산용 분산제(NPS)를 제조 하였다. 합성한 분산제의 자외선 흡수 곡선은 PNS와 비슷하여 다양한 나프탈렌 유도체의 구조임을 알 수 있었다. NPS는 시멘트, 산화철 및 탄산칼슘 등 무기입자들의 분산계에 이용할 수 있는 우수한 성능을 나타내었다.

Dispersants were prepared from petroleum pyrolysis residual oil (PPRO) through sulfonation. Without employing a conventional polynaphthalene sulfonate formaldehyde condensate (PNS) process, the dispersants (NPS) were synthesized by a simpler process only in 2 h. The chemical structure of new dispersant, which has various naphthalene derivative groups, was similar to PNS conformed by UV-visible spectroscopy curves. The new dispersants demonstrated high dispersing ability in inorganic suspension ; cement, Fe2O3, and CaCO3.

Keywords:dispersant;petroleum pyrolysis residual oil (PPRO);sulfonation

[References]

Lee GS, New Surfactant, Se Hwa, 435 (1994)
Eckard A, Riff I, Weaver J, Formulation of soluble oils with synthetic and petroleum sulfonation, J. Soc. Trbol. & Lub. Eng., 17∼22 (1997)
Lesnyak VP, Gaponik LV, Mardykin VP, Kaputskii FN, Russ. J. Appl. Chem., Gel filteration chromatography of pertoleum sulfonates, 76, 1870 (2003)
Ogata E, Yanase N, Kitahara T, Sulfonating agent and sulfonation process, US PAT 5,596,128 (1997)
Green shield & Herbert peterge, Dispersant and it used dispersion, KR PAT 2000-7000768 (2003)
Ng WL, Rana D, Neale GH, Hornof V, J. Appl. Polym. Sci., 88(4), 860 (2003)
Wang HY, Li MY, Wu ZL, Lin MQ, Chin. J. Chem. Eng., 13(5), 691 (2005)
Suzyki S, Yamauchi A, Kiyama S, Yamaki K, Method for preparing dispersing agent, US PAT 3,970,690 (1976)
Choi SW, Oh NH, Kwon OY, Seo HJ, Kwon YB, J. Korea Solid Waste Eng. Soc., 14, 1666 (1997)
Brudckmann R, Bury W, Dix JP, Herrmann M, Dlugosch W, Kromm E, Letter H, Zimmermann N, Kermer W, Taeger K, Dye dispersants: aryl sulphonic acid-formaldehyde condensate or ligninsulfonate, US PAT 5,186,846 (1993)
Rho JS, Cho HY, Hong SS, Chem. Ind. & Tec., Research trend and subject of cement concrete surfactants, 12, 397 (1994)
Lee JM, Ko JC, Kim BS, Han MW, Continuous manufacturing method that new manufacture system with aromatic sulfuric acid, KR PAT 1993-0014239 (1993)
Sami Matar, Kerosens Chemistry Curriculum, Intervision 41 (2000)
Stephen Y, Bush LL, Process for graftig lignin with vinylic monomers using separate streams of initiator and monomer, US PAT 4,891,415F (1990)
Rui Z, Sonmasundaran P, Adv. Colloid Interface Sci., 303, 213 (2006)
Adamczyk Z, Zembala A, Michna A, J. Colloid Interface Sci., 303(2), 353 (2006)
Zhang L, Somasundaran P, Maltesh C, J. Colloid Interface Sci., 191(1), 202 (1997)
Matsui M, Effect of the salt in adsorption behavior of high reducing agent, Cement & Concrete, 43, 90 (1989)
Silverstein RM, Bassler GC, Morrill TC, Spectromertic indetification of organic compounds, 4th ed., John willey & Sons, INC, 289 (1991)

[Referenced By]

[1] Lee GS, New Surfactant, Se Hwa, 435 (1994)

[2] Eckard A, Riff I, Weaver J, Formulation of soluble oils with synthetic and petroleum sulfonation, J. Soc. Trbol. & Lub. Eng., 17∼22 (1997)

[3] Lesnyak VP, Gaponik LV, Mardykin VP, Kaputskii FN, Russ. J. Appl. Chem., Gel filteration chromatography of pertoleum sulfonates, 76, 1870 (2003)

[4] Ogata E, Yanase N, Kitahara T, Sulfonating agent and sulfonation process, US PAT 5,596,128 (1997)

[5] Green shield & Herbert peterge, Dispersant and it used dispersion, KR PAT 2000-7000768 (2003)

[6] Ng WL, Rana D, Neale GH, Hornof V, J. Appl. Polym. Sci., 88(4), 860 (2003)

[7] Wang HY, Li MY, Wu ZL, Lin MQ, Chin. J. Chem. Eng., 13(5), 691 (2005)

[8] Suzyki S, Yamauchi A, Kiyama S, Yamaki K, Method for preparing dispersing agent, US PAT 3,970,690 (1976)

[9] Choi SW, Oh NH, Kwon OY, Seo HJ, Kwon YB, J. Korea Solid Waste Eng. Soc., 14, 1666 (1997)

[10] Brudckmann R, Bury W, Dix JP, Herrmann M, Dlugosch W, Kromm E, Letter H, Zimmermann N, Kermer W, Taeger K, Dye dispersants: aryl sulphonic acid-formaldehyde condensate or ligninsulfonate, US PAT 5,186,846 (1993)

[11] Rho JS, Cho HY, Hong SS, Chem. Ind. & Tec., Research trend and subject of cement concrete surfactants, 12, 397 (1994)

[12] Lee JM, Ko JC, Kim BS, Han MW, Continuous manufacturing method that new manufacture system with aromatic sulfuric acid, KR PAT 1993-0014239 (1993)

[13] Sami Matar, Kerosens Chemistry Curriculum, Intervision 41 (2000)

[14] Stephen Y, Bush LL, Process for graftig lignin with vinylic monomers using separate streams of initiator and monomer, US PAT 4,891,415F (1990)

[15] Rui Z, Sonmasundaran P, Adv. Colloid Interface Sci., 303, 213 (2006)

[16] Adamczyk Z, Zembala A, Michna A, J. Colloid Interface Sci., 303(2), 353 (2006)

[17] Zhang L, Somasundaran P, Maltesh C, J. Colloid Interface Sci., 191(1), 202 (1997)

[18] Matsui M, Effect of the salt in adsorption behavior of high reducing agent, Cement & Concrete, 43, 90 (1989)

[19] Silverstein RM, Bassler GC, Morrill TC, Spectromertic indetification of organic compounds, 4th ed., John willey & Sons, INC, 289 (1991)