As(V) oxyanions removal from aqueous systems by dissolved air flotation (DAF) using Fe2O3 center dot xH(2)O as solid support and sodium laurate as anionic surfactant was investigated. The influencing factors of the process: pH, support, surfactant, and As(V) concentrations, the presence of flocculant and foreign ions, conditioning time and dissolved air pressure were discussed, as they may affect in a great extent the separation efficiency. The systematic study aims to establish the optimum operating parameters of the process, to investigate the equilibrium and mechanism of separation.