Journal of Chemical Thermodynamics, Vol.39, No.2, 254-260, 2007
Compressed liquid densities of 1-butanol and 2-butanol at temperatures from 313 K to 363 K and pressures up to 25 MPa
(p, rho, T) properties were determined in liquid phase for 1-butanol and 2-butanol at temperatures from 3 3 13 K to 363 K and pressures up to 25 MPa using a vibrating tube densimeter. The uncertainty is estimated to be lower than +/- 0.2 kg (.) m(-3) for the experimental densities. Nitrogen and water were used as reference fluids for the calibration of the vibrating tube densimeter. Experimental densities of 1-butanol and 2-butanol were correlated with a short empirical equation and the 11-parameter Benedict-Webb-Rtibin-Starling equation of state (BWRS EoS) using a least square optimization. Statistical values to evaluate the different correlations were reported. Published densities of 1-butanol and 2-butanol are compared with values calculated with the BWRS EoS using the parameters obtained in this work. The experimental data determined here are also compared with available correlations for 1-butanol and 2-butanol. (c) 2006 Elsevier Ltd. All rights reserved.