High-performance microcellular closed-cell foams were prepared by a two-stage batch foaming process from fluorinated poly(ether ether ketone) and characterized by scanning electronic microscopy, tensile, and dynamic mechanical analysis (DMA). The effects of saturation pressure and temperature on the cell size, cell density, and bulk density of porous materials had been discussed. The resulting materials had average cell diameters in the range 3-17 mu m, and cell densities (N-f) in the order of 0.6 x 10(9)-1.39 x 10(10) cells/cm(3). The porosity (V-f) was in the range of 0.2-0.85. In contrast, experimental values of Young's moduli were in good agreement with theoretically predicted values, but the relative strengths were somewhat lower than that predicted. The relaxation mechanism of microcellular was systematically investigated by DMA. The dynamic mechanical spectrometry showed that the storage modulus curve at high temperature region appeared a peak and the loss modulus was lower as compared to their solid counterparts. (c) 2006 Wiley Periodicals, Inc.