화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.24, No.2, 350-353, March, 2007
Synthesis of dimethyl ether from syngas obtained by coal gasification
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The characteristics of a tubular fixed-bed reactor for the direct synthesis of dimethyl ether (DME) from syngas obtained by coal gasification have been developed. DME synthesis test was conducted with a hybrid DME synthesis catalyst (CuO/ZnO/Al2O3 for methanol forming, γ-alumina for methanol dehydration) to understand the performance under the conditions of 6.0MPa, 260 ℃ and GHSV=3,000 l/kg-cat·h. The H2 conversion and CO conversion were 85-92%, 37-45%, respectively. About 68-80% of DME selectivity was observed. DME synthesis reactor also operated at the productivity of 4.6-4.9 mol/kg-cat·h, which is slightly higher than that in the Peng’s prediction results in case of H2 : CO=0.5.
  1. Larson ED, Ren T, Energy for Sustainable Development, VII, 79 (2003)
  2. Ohno Y, Advanced clean coal technology international symposium, 1 (1999)
  3. Heydorn EC, Diamond BW, Lilly RD, Final Report to the National Energy Technology Laboratory, US Department of Energy, under Cooperative Agreement No. DE-FC22-92PC90543 (2003)
  4. Peng XD, Wang AW, Toseland BA, Tijm PJ, Ind. Eng. Chem. Res., 38, 4381 (1999)
  5. Hu JL, Wang Y, Cao CS, Elliott DC, Stevens DJ, White JF, Ind. Eng. Chem. Res., 44(6), 1722 (2005)