Combustion characteristics of vacuum residue in a test furnace and its utilization for utility boiler

Ho Yong Park; Young Ju Kim

Korean Journal of Chemical Engineering, Vol.24, No.1, 83-92, January, 2007

DOI10.1007/s11814-007-5014-3 Export Citation

Combustion characteristics of vacuum residue in a test furnace and its utilization for utility boiler

Ho Yong Park^†, and Young Ju Kim

Power Generation Laboratory, Korea Electric Power Research Institute, 103-16 Munji-dong, Yusung-gu, Daejeon 305-380, Korea

E-mail:

Recently, increased attention has been exerted on the utilization of cheaper hydrocarbons fuel such as Vacuum Residue (VR). As a fundamental investigation for VR utilization, VR combustion tests were carried out in a test furnace with a fuel feed rate of 20 kg/h. As compared with heavy oil, VR used in this work is much more viscous and contains high percentages of sulfur, carbon residue and heavy metals. Successful fuel transportation and atomization has been achieved with the indirect heating of fuel by a thermia oil. The measured distributions of temperature, major species concentrations and solid samples along with the furnace revealed that the main reaction zone remains within about 1 m from the burner tip and the characteristics of VR flame are dependent on the ratio of fuel/air feeding rate. VR carbonaceous particles collected along with the furnace showed that their complete conversion would be a very essential factor for the utilization of VR as a fuel. Several issues for applying it to utility boilers have been investigated in line with the present results, and some suggestions have been made.

Keywords:Vacuum Residue;Carbon Residue;Atomization;Viscosity

[References]

Aoki H, Fukushima H, Yoshida T, The Thermal and Nuclear Power, 55, 1356 (2004)
Basu P, Kefa C, Jestin L, Boilers and burners, Springer, New York (2000)
Chigier N, Combustion measurements, Hemisphere Publishing Corporation, New York (1991)
Choi YC, Lee JG, Yoon SJ, Park MH, Korean J. Chem. Eng., 23 (2006)
Clayton RM, Back LH, Journal of Engineering for Gas Turbines and Power, 111, 679 (1989)
Cullis CF, Mulcahy MFR, Combustion and Flame, 18, 225 (1972)
Fujimura K, Mastumoto H, Arakawa Y, Fujii H, Mizoguchi T, Mitsubishi Juco Giho, See also http://www. mhi.co.jp/tech/htm/ 9362/e936211a.htm, 36 (1999)
Gollahalli SR, Nasrullah MK, Bhashi JH, Combustion and Flame, 55, 93 (1984)
Gray MR, Upgrading petroleum residues and heavy oils, Marcel Dekker, Inc., New York (1994)
Glassman I, Combustion, 2nd Ed., Academic Press, Orlando (1987)
Hashimoto A, Ichinose T, Fujimura K, Kaneko S, Hishida M, Arakawa Y, Mitsubishi Juco Giho, See also http://www. mhi.co.jp/tech/htm/8351/e835108a.htm, 35 (1998)
Ichinose T, Fujimura K, Takeno K, Motai T, Arakawa Y, Fujii H, JSME International Journal, 41, 1055 (1998)
Lefebre H, Atomization and sprays, Hemisphere Publishing Corporation, New York (1989)
Linak WP, Miller CA, Santoianni DA, King CJ, Shinagawa T, Wendt JOL, Yoo JI, Seo YC, Korean J. Chem. Eng., 20(4), 664 (2003)
Ma J, Fletcher TH, Webb BW, “Conversion of coal tar to soot during coal pyrolysis in a post-flame environment,” Twenty-Sixthh Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, 3161 (1996)
Marrone NJ, Kennedy IM, Dryer FL, Combust. Sci. Technol., 36, 149 (1984)
Miller JA, Bowman CT, Prog. Energy Combust. Sci., 15, 287 (1989)
Nenniger RD, Howard JB, Sarofim AF, “Sooting potential of coals,” International Conference on Coal Science, Pittsburgh, 521 (1983)
Moleo LJ, Pollutant formation and interaction in the combustion of heavy liquid fuels, PhD thesis, University college London (1998)
Northrop PS, Gavalas GR, Energy Fuels, 5, 587 (1991)
Moszkowicz P, Witzel L, Claus G, Chem. Eng. Sci., 51(17), 4075 (1996)
Park HY, Kim TH, Energy Conv. Manag., 47(15-16), 2118 (2006)
Park HY, Seo SI, International Journal of Energy Research, 30, 365 (2006)
Pfefferle LD, Churchill SW, Combustion Science and Technology, 48, 235 (1986)
Richter H, Howard JB, Prog. Energy Combust. Sci., 26, 565 (2000)
Seeker WR, Samuelsen GS, Heap MP, Trolinger JD, “Thermal decomposition of pulverised coal particles,” Eighteenth Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, 1213 (1980)
Serio MA, Hamblen DG, Markham JR, Solomon PP, Energy Fuels, 1, 138 (1987)
Simbeck D, Johnson H, “World gasification survey: Industry trends & developments,” Gasification Technologies 2001 Conference, San Francisco, CA (2001)
Singer JG, Combustion fossil power, Combustion Engineering, Inc. Rand McNally (1991)
Sonoda T, Komori T, Kato M, Kitauchi Y, Iwasaki Y, Akizuki W, Hashi T, Kunihiro K, “Development of M701F gas turbine for integrated gasification combined cycle plants,” Technical Review, 41, Mitsubishi Heavy Industries. Ltd. (2004)
Timothy LD, Froelich D, Sarofim AF, Beer JM, “Soot formation and burnout during the combustion of dispersed pulverised coal particles,” Twenty-First Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, 1141 (1986)
Urban DL, Huey SPC, Dryer FL, “Evaluation of the coke formation potential of residual fuel oils,” Twenty-Fourth Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, 1357 (1992)
Villasenor R, Escalera R, International Journal of Heat and Mass Transfer, 41, 3087 (1998)
Villasenor R, Garcia F, Fuel, 78(8), 933 (1999)
Wolff J, Radtke K, Karg J, Gunster W, “Refinery residue based IGCC power plants and market potential,” Gasification Technologies 2001 Conference, San Francisco, CA (2001)

[Referenced By]

[1] Aoki H, Fukushima H, Yoshida T, The Thermal and Nuclear Power, 55, 1356 (2004)

[2] Basu P, Kefa C, Jestin L, Boilers and burners, Springer, New York (2000)

[3] Chigier N, Combustion measurements, Hemisphere Publishing Corporation, New York (1991)

[4] Choi YC, Lee JG, Yoon SJ, Park MH, Korean J. Chem. Eng., 23 (2006)

[5] Clayton RM, Back LH, Journal of Engineering for Gas Turbines and Power, 111, 679 (1989)

[6] Cullis CF, Mulcahy MFR, Combustion and Flame, 18, 225 (1972)

[7] Fujimura K, Mastumoto H, Arakawa Y, Fujii H, Mizoguchi T, Mitsubishi Juco Giho, See also http://www. mhi.co.jp/tech/htm/ 9362/e936211a.htm, 36 (1999)

[8] Gollahalli SR, Nasrullah MK, Bhashi JH, Combustion and Flame, 55, 93 (1984)

[9] Gray MR, Upgrading petroleum residues and heavy oils, Marcel Dekker, Inc., New York (1994)

[10] Glassman I, Combustion, 2nd Ed., Academic Press, Orlando (1987)

[11] Hashimoto A, Ichinose T, Fujimura K, Kaneko S, Hishida M, Arakawa Y, Mitsubishi Juco Giho, See also http://www. mhi.co.jp/tech/htm/8351/e835108a.htm, 35 (1998)

[12] Ichinose T, Fujimura K, Takeno K, Motai T, Arakawa Y, Fujii H, JSME International Journal, 41, 1055 (1998)

[13] Lefebre H, Atomization and sprays, Hemisphere Publishing Corporation, New York (1989)

[14] Linak WP, Miller CA, Santoianni DA, King CJ, Shinagawa T, Wendt JOL, Yoo JI, Seo YC, Korean J. Chem. Eng., 20(4), 664 (2003)

[15] Ma J, Fletcher TH, Webb BW, “Conversion of coal tar to soot during coal pyrolysis in a post-flame environment,” Twenty-Sixthh Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, 3161 (1996)

[16] Marrone NJ, Kennedy IM, Dryer FL, Combust. Sci. Technol., 36, 149 (1984)

[17] Miller JA, Bowman CT, Prog. Energy Combust. Sci., 15, 287 (1989)

[18] Nenniger RD, Howard JB, Sarofim AF, “Sooting potential of coals,” International Conference on Coal Science, Pittsburgh, 521 (1983)

[19] Moleo LJ, Pollutant formation and interaction in the combustion of heavy liquid fuels, PhD thesis, University college London (1998)

[20] Northrop PS, Gavalas GR, Energy Fuels, 5, 587 (1991)

[21] Moszkowicz P, Witzel L, Claus G, Chem. Eng. Sci., 51(17), 4075 (1996)

[22] Park HY, Kim TH, Energy Conv. Manag., 47(15-16), 2118 (2006)

[23] Park HY, Seo SI, International Journal of Energy Research, 30, 365 (2006)

[24] Pfefferle LD, Churchill SW, Combustion Science and Technology, 48, 235 (1986)

[25] Richter H, Howard JB, Prog. Energy Combust. Sci., 26, 565 (2000)

[26] Seeker WR, Samuelsen GS, Heap MP, Trolinger JD, “Thermal decomposition of pulverised coal particles,” Eighteenth Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, 1213 (1980)

[27] Serio MA, Hamblen DG, Markham JR, Solomon PP, Energy Fuels, 1, 138 (1987)

[28] Simbeck D, Johnson H, “World gasification survey: Industry trends & developments,” Gasification Technologies 2001 Conference, San Francisco, CA (2001)

[29] Singer JG, Combustion fossil power, Combustion Engineering, Inc. Rand McNally (1991)

[30] Sonoda T, Komori T, Kato M, Kitauchi Y, Iwasaki Y, Akizuki W, Hashi T, Kunihiro K, “Development of M701F gas turbine for integrated gasification combined cycle plants,” Technical Review, 41, Mitsubishi Heavy Industries. Ltd. (2004)

[31] Timothy LD, Froelich D, Sarofim AF, Beer JM, “Soot formation and burnout during the combustion of dispersed pulverised coal particles,” Twenty-First Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, 1141 (1986)

[32] Urban DL, Huey SPC, Dryer FL, “Evaluation of the coke formation potential of residual fuel oils,” Twenty-Fourth Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, 1357 (1992)

[33] Villasenor R, Escalera R, International Journal of Heat and Mass Transfer, 41, 3087 (1998)

[34] Villasenor R, Garcia F, Fuel, 78(8), 933 (1999)

[35] Wolff J, Radtke K, Karg J, Gunster W, “Refinery residue based IGCC power plants and market potential,” Gasification Technologies 2001 Conference, San Francisco, CA (2001)