Journal of Physical Chemistry B, Vol.110, No.43, 21846-21849, 2006
Observation of single dinuclear metal-complex molecules using scanning tunneling microscopy
We report a scanning tunneling microscopy (STM) investigation of a dinuclear organometallic molecule, trans-[Cl(dppe)(2)Ru(C C)(6)Ru(dppe)(2)Cl] (Ru-2), absorbed on a Au(111) surface; this molecule is a potential candidate for use in molecular quantum-dot cellular automata (QCA) devices. Isolated Ru2 molecules were observed under ultra-high-vacuum conditions. Submolecular structure was clearly discernible in the STM images, with a bright feature corresponding to each of the two Ru-ligand complexes within the Ru2 molecule. Rotation and translation of the Ru2 molecules were observed to be induced by the STM tip under some tunneling conditions.