Novel metalloreagent cp(CO)(2)FeP(Se)(OR)(2) produced from P-Se bond cleavage in the thermal reaction of [CpFe(CO)(2)](2) with phosphor-1,1-diselenolates

Liu CW; Chen JM; Santra BK; Wen SY; Liaw BJ; Wang JC

Inorganic Chemistry, Vol.45, No.22, 8820-8822, 2006

Liu CW, Chen JM, Santra BK, Wen SY, Liaw BJ, Wang JC

The reaction of [ CpFe( CO)(2)](2) with NH4Se2P( OR)(2) yields a novel reagent Cp( CO)(2)FeP( Se)( OR)(2), which has demonstrated coordination properties at the Se center to form heterometallic clusters as well as reactivity at the Se site toward C-based electrophiles.