Field-induced alignment of O-2 and N-2 was experimentally studied with laser intensities varying from 10(13) to 10(15) W/cm(2). When the laser intensity was below the ionization threshold for these molecules, the interaction between the induced dipole moment of molecules and the laser electric field aligned the molecules along the laser polarization direction. After extinction of the exciting laser, the transient alignment revived periodically. Thus macroscopic ensembles of highly aligned O-2 and N-2 molecules were obtained under field-free conditions. When the laser intensity exceeded the ionization threshold for these molecules, multielectron ionization and Coulomb explosion occurred. Using two linearly polarized laser pulses with crossed polarization, we demonstrated that the rising edge of the laser pulse aligned the molecules along the laser polarization direction prior to ionization, which resulted in strong anisotropic angular distributions of exploding fragments. These results suggest that the degree of alignment should be taken into account when qualitatively comparing the ion yield of these molecules with their companion atoms.