A multiscale FD-KMC model has been developed to simulate the cyclic voltammetry test of a copper electrode in simple copper sulfate bath. In this coupled model, the FD code provides the cupric ion concentration on OHP for KMC code, while the KMC code provides the electrochemical properties of the copper electrode (surface activity and rate constants of redox reactions) as an input data for FD code. The changes in the electrode properties due to the atomistic phenomena (deposition dissolution and surface diffusion) have been studied for the present potentiodynamic system. The results showed that the CV process consists of some distinct stages, so that the electrode exhibits a specific morphology and electrochemical behavior in each one. (c) 2006 Elsevier B.V. All rights reserved.