Journal of Applied Polymer Science, Vol.101, No.4, 2656-2660, 2006
Preparation of epoxy resin/CaCO3 nanocomposites and performance of resultant powder coatings
Epoxy resin/CaCO3 nanocomposites were prepared by the methods of extruding, solution blending, and in situ and inclusion polymerization, respectively. The contents of nanoparticles in the nanocomposites were varied from 5 wt % to 15 wt %. Powder coatings with different content of nanoparticles were made from the nanocomposites. The results showed that the cupping property and impact resistance decreased with the increase of coating film thickness. The dispersion of nanoparticles in epoxy matrix affected the impact resistance and cupping property of the obtained coating films greatly. The coating films made from the nanocomposite prepared by in situ and inclusion polymerization showed that the best impact resistance and the maximum cupping property was achieved when nano-CaCO3, content was 5 wt %. (c) 2006 Wiley Periodicals, Inc.