화학공학소재연구정보센터
Chemical Engineering Science, Vol.54, No.13-14, 2889-2898, 1999
Reversed flow converter for emission control after automotive engines
A concept of catalytic reversed flow converter (RFC) is discussed for three emerging areas of emission control after automotive engines. The first potential application concerns with oxidation of methane and CO emitted from dual fueled, natural gas/diesel engines (DDF). The behavior of RFC is studied under typical transient conditions of DDF engine exhaust using mathematical modeling and experiments with converter prototype. It was shown that the RFC with a single catalyst monolith can be well suited for this application. The second potential application is aimed at NOx emission control from diesel engines. An RFC comprising a catalyst bed flanked by two beds of inert material is discussed based on a lumped kinetics of NOx reduction over a noble metal lean-NOx catalyst. Contrary to a traditional converter, the RFC retains high efficiency of NOx reduction for long time after typical excursion of NOx concentration and temperature of engine exhaust gas. Finally, an idea of RFC combining catalyst and adsorbent is suggested for emission control during cold start of automotive engines.