화학공학소재연구정보센터
Journal of Colloid and Interface Science, Vol.297, No.2, 772-777, 2006
Contact angle hysteresis of cylindrical drops on chemically heterogeneous striped surfaces
Contact angle hysteresis of a macroscopic droplet on a heterogeneous but flat substrate is studied using the interface displacement model. First, the apparent contact angle of a droplet on a heterogeneous Surface under the condition of constant volume is considered. By assuming a cylindrical liquid-vapor surface (meniscus) and minimizing the total free energy, we derive an equation for the apparent contact angle, which is similar but different from the well-known Cassie's law. Next, using this modified Cassie's law as a guide to predict the behavior of a droplet on a heterogeneous striped surface. we examine several scenarios of contact angle hysteresis using a periodically striped Surface model. By changing the Volume of the droplet, we predict a Sudden jump of the droplet edge, and it continuous change of the apparent contact angle at the edge of two Stripes. Our results suggest that as drop volume is increased (advancing contact lines), the predominant drop configuration observed is the one whose contact angle is large whereas, decreasing drop volume from a large value (receding contact lines) yields drop configuration that predominantly exhibit the smaller contact angle. (c) 2005 Elsevier Inc. All rights reserved.