Polymerization of Borazine with Tetramethyldivinyldisilazane as a New Class SiCBN Preceramic Polymer

Quoc Dat Nghiem; Dong-Pyo Kim

Journal of Industrial and Engineering Chemistry, Vol.12, No.6, 905-910, November, 2006

Export Citation

Polymerization of Borazine with Tetramethyldivinyldisilazane as a New Class SiCBN Preceramic Polymer

Quoc Dat Nghiem, and Dong-Pyo Kim^†

Department of Fine Chemical Engineering & Chemistry, Chungnam National University, Daejeon 305-764, Korea

E-mail:

Borazine derivatives were reacted with divinyldisilazane via hydroboration reactions. The synthesized liquid polymer with a ca. 70 % ceramic yield changed to an insoluble solid after crosslinking reactions of the unreacted vinyl groups to the B-C alkyl bridges between the borazine ring and vinylsilazane as post-heated from 200 to 600 ℃. The insoluble solid was then transformed to SiCN and BN amorphous structures when pyrolyzed to 1400 ℃. The process of the synthetic and ceramic conversion was thoroughly investigated by infrared, 1H, 11B, 13C, and 29Si nuclear magnetic resonance spectroscopy, and thermal gravimetric analysis.

Keywords:hydroboration;preceramic polymer;SiCBN ceramic;borazine;vinylsilazanes

[References]

Bill J, Aldinger F, Adv. Mater., 7, 775 (1995)
Paine RT, Narula CK, Chem. Rev., 90, 73 (1990)
Seyferth D, Rees WS, Chem. Mater., 3, 1106 (1991)
Hong LY, Kim DJ, Kim DP, J. Ind. Eng. Chem., 10(6), 936 (2004)
Riedel R, Kienzle A, Dressler W, Ruwisch L, Bill J, Aldinger F, Nature, 382(6594), 796 (1996)
Weinmannn M, Kamphowe TW, Schuhmacher J, Muller K, Aldinger F, Chem. Mater., 12, 2116 (2000)
Ruwisch LM, Durichen P, Riedel R, Polyhedron, 19, 323 (2000)
Schmidt WR, Narsavage-Heald DM, Jones DM, Marchetti PS, Raker D, Maciel GE, Chem. Mater., 11, 1455 (1999)
Weinmann M, Schuhmacher J, Kummer H, Prinz S, Peng J, Seifert HJ, Christ M, Muller K, Bill J, Aldinger F, Chem. Mater., 12, 623 (2000)
Seyferth D, Plenio HJ, J. Am. Ceram. Soc., 73, 2131 (1990)
Haberecht J, Krumeich F, Grutzmacher H, Nesper R, Chem. Mater., 16, 418 (2004)
Haberecht J, Nesper R, Grutzmacher H, Chem. Mater., 17, 2340 (2005)
Srivastava D, Duesler EN, Paine RT, Eur. J. Inorg. Chem., 855 (1998)
Su K, Remsen EE, Zank GA, Sneddon LG, Chem. Mater., 5, 547 (1993)
Wideman T, Su K, Remsen EE, Zank GA, Sneddon LG, Chem. Mater., 7, 2203 (1995)
Wideman T, Cortez E, Remsen EE, Zank GA, Carroll PJ, Sneddo LG, Chem. Mater., 9, 2218 (1997)
Jeon JK, Uchimaru Y, Kim DP, Inorg. Chem., 43(16), 4796 (2004)
Nghiem QD, Jeon JK, Hong LY, Kim DP, J. Org. Chem., 688, 27 (2003)
Jeon JK, Nghiem QD, Kim DP, Lee LY, J. Org. Chem., 689, 2311 (2004)
Moon KT, Min DS, Kim DP, Bull. Korean Chem. Soc., 19, 222 (1998)
Schiavon MA, Sorary GD, Yoshyda IVP, J. Non-Cryst. Solids, 304, 76 (2002)
Gerardin C, Taulelle F, Bahloul D, J. Mater. Chem., 7, 117 (1997)
Kortobi Y, Shihi H, Legrand AP, Musset E, Herlin N, Cauchetier M, Colloids Surf. A: Physicochem. Eng. Asp., 115, 319 (1996)
Schuhmacher J, Berger F, Weinmann M, Bill J, Aldinger F, Muller K, Appl. Organomet. Chem., 15, 809 (2001)
Gervais C, Maquet J, Babonneau F, Duriez C, Framery E, Vaultier M, Florian P, Massiot D, Chem. Mater., 13, 1700 (2001)
Muller A, Zern A, Gerstel P, Bill J, Aldinger F, J. Eur. Ceram. Soc., 22, 1631 (2002)
Muller A, Peng J, Seifert HJ, Bill J, Aldinger F, Chem. Mater., 14, 3406 (2002)

[Referenced By]

[Related Articles]

[1] Bill J, Aldinger F, Adv. Mater., 7, 775 (1995)

[2] Paine RT, Narula CK, Chem. Rev., 90, 73 (1990)

[3] Seyferth D, Rees WS, Chem. Mater., 3, 1106 (1991)

[4] Hong LY, Kim DJ, Kim DP, J. Ind. Eng. Chem., 10(6), 936 (2004)

[5] Riedel R, Kienzle A, Dressler W, Ruwisch L, Bill J, Aldinger F, Nature, 382(6594), 796 (1996)

[6] Weinmannn M, Kamphowe TW, Schuhmacher J, Muller K, Aldinger F, Chem. Mater., 12, 2116 (2000)

[7] Ruwisch LM, Durichen P, Riedel R, Polyhedron, 19, 323 (2000)

[8] Schmidt WR, Narsavage-Heald DM, Jones DM, Marchetti PS, Raker D, Maciel GE, Chem. Mater., 11, 1455 (1999)

[9] Weinmann M, Schuhmacher J, Kummer H, Prinz S, Peng J, Seifert HJ, Christ M, Muller K, Bill J, Aldinger F, Chem. Mater., 12, 623 (2000)

[10] Seyferth D, Plenio HJ, J. Am. Ceram. Soc., 73, 2131 (1990)

[11] Haberecht J, Krumeich F, Grutzmacher H, Nesper R, Chem. Mater., 16, 418 (2004)

[12] Haberecht J, Nesper R, Grutzmacher H, Chem. Mater., 17, 2340 (2005)

[13] Srivastava D, Duesler EN, Paine RT, Eur. J. Inorg. Chem., 855 (1998)

[14] Su K, Remsen EE, Zank GA, Sneddon LG, Chem. Mater., 5, 547 (1993)

[15] Wideman T, Su K, Remsen EE, Zank GA, Sneddon LG, Chem. Mater., 7, 2203 (1995)

[16] Wideman T, Cortez E, Remsen EE, Zank GA, Carroll PJ, Sneddo LG, Chem. Mater., 9, 2218 (1997)

[17] Jeon JK, Uchimaru Y, Kim DP, Inorg. Chem., 43(16), 4796 (2004)

[18] Nghiem QD, Jeon JK, Hong LY, Kim DP, J. Org. Chem., 688, 27 (2003)

[19] Jeon JK, Nghiem QD, Kim DP, Lee LY, J. Org. Chem., 689, 2311 (2004)

[20] Moon KT, Min DS, Kim DP, Bull. Korean Chem. Soc., 19, 222 (1998)

[21] Schiavon MA, Sorary GD, Yoshyda IVP, J. Non-Cryst. Solids, 304, 76 (2002)

[22] Gerardin C, Taulelle F, Bahloul D, J. Mater. Chem., 7, 117 (1997)

[23] Kortobi Y, Shihi H, Legrand AP, Musset E, Herlin N, Cauchetier M, Colloids Surf. A: Physicochem. Eng. Asp., 115, 319 (1996)

[24] Schuhmacher J, Berger F, Weinmann M, Bill J, Aldinger F, Muller K, Appl. Organomet. Chem., 15, 809 (2001)

[25] Gervais C, Maquet J, Babonneau F, Duriez C, Framery E, Vaultier M, Florian P, Massiot D, Chem. Mater., 13, 1700 (2001)

[26] Muller A, Zern A, Gerstel P, Bill J, Aldinger F, J. Eur. Ceram. Soc., 22, 1631 (2002)

[27] Muller A, Peng J, Seifert HJ, Bill J, Aldinger F, Chem. Mater., 14, 3406 (2002)