Second Harmonic Generation and Fabrication of Transparent K2O-Na2O-Nb2O5-TeO2 Glass-Ceramics

Euh Duck Jeong; Pramod H. Borse; Jae Sung Lee; Myoung Gyu Ha; Hyuk Kyu Pak; Takayuki Komatsu; Hyun Gyu Kim

Journal of Industrial and Engineering Chemistry, Vol.12, No.5, 790-794, September, 2006

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Second Harmonic Generation and Fabrication of Transparent K2O-Na2O-Nb2O5-TeO2 Glass-Ceramics

Euh Duck Jeong, Pramod H. Borse¹, Jae Sung Lee¹, Myoung Gyu Ha, Hyuk Kyu Pak, Takayuki Komatsu², and Hyun Gyu Kim^†

Busan Center, Korea Basic Science Institute/Dept. of Physics, Pusan National University, Busan 609-735, Korea
¹Department of Chemical Engineering, Pohang University of Science and Technology, Pohang 790-784, Korea
²Department of Chemistry, Nagaoka University of Technology, Nagaoka 940-21, Japan

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To develop and utilize TeO2-based glasses as nonlinear optical materials or matrix glasses, xK2O-(14-x)Na2O-14Nb2O5-72TeO2 (x=0～14 mol%) glasses were prepared using a conventional melt quenching method and then the nano-crystallization behavior and second harmonic generation (SHG) properties of these glasses were investigated. Although SHG was clearly observed in 10K2O-4Na2O-14Nb2O5-72TeO2 glassceramics consisting of a nano-crystalline phase, the 14Na2O-14Nb2O5-72TeO2 glass-ceramic exhibited no SHG. K+ ions played an important role in inducing SHG in the K2O-Na2O-Nb2O5-TeO2 system.

Keywords:SHG;nano-crystals;nonlinear optical materials;glass-ceramics

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Heo J, Lam D, Sigel G, Mendoza E, Hensley D, J. Am. Ceram. Soc., 75, 277 (1992)
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Shioya K, Komatsu T, Kim HG, Sato R, Komatsu K, J. Non-Cryst. Solids, 189, 16 (1995)
Kim HG, Komatsu T, Shioya K, Sato R, Komatsu K, Tanaka K, Hirao K, J. Non-Cryst. Solids, 208, 303 (1996)
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Kim SH, Yoko T, J. Am. Ceram. Soc., 78, 1061 (1995)
Lin KL, J. Ind. Eng. Chem., 11(6), 834 (2005)
Ray JC, Park DW, Ahn WS, J. Ind. Eng. Chem., 12(1), 142 (2006)
Yoon KR, Jung C, Rhee BK, Lee H, J. Ind. Eng. Chem., 11(6), 852 (2005)
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Komatus T, Shioya K, J. Non-Cryst. Solids, 209, 305 (1997)
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Subramanian MA, Aravamudan G, Rao GVS, Prog. Solid State Chem., 15, 55 (1983)

[Related Articles]

[1] Stanworth JE, Nature, 169, 581 (1952)

[2] El-Mallawany R, J. Mater. Res., 7, 224 (1992)

[3] Heo J, Lam D, Sigel G, Mendoza E, Hensley D, J. Am. Ceram. Soc., 75, 277 (1992)

[4] Abdel-Kader A, Elkholy M, J. Appl. Phys., 73, 71 (1993)

[5] Wang JS, Vogel EM, Snitzer E, Opt. Mater., 3, 187 (1994)

[6] Balaya P, Sunandana CS, J. Non-Cryst. Solids, 162, 253 (1993)

[7] Sekiya T, Mochida N, Ohtsuka A, J. Non-Cryst. Solids, 185, 135 (1995)

[8] Sekiya T, Mochida N, Soejima A, J. Non-Cryst. Solids, 191, 115 (1995)

[9] Shioya K, Komatsu T, Kim HG, Sato R, Komatsu K, J. Non-Cryst. Solids, 189, 16 (1995)

[10] Kim HG, Komatsu T, Shioya K, Sato R, Komatsu K, Tanaka K, Hirao K, J. Non-Cryst. Solids, 208, 303 (1996)

[11] Kim HG, Komatsu T, Sato R, Komatsu K, J. Non-Cryst. Solids, 162, 201 (1993)

[12] Tanaka K, Kashima K, Hirao K, Soga N, Mito A, Nasu H, J. Non-Cryst. Solids, 185, 123 (1995)

[13] Kim SH, Yoko T, J. Am. Ceram. Soc., 78, 1061 (1995)

[14] Lin KL, J. Ind. Eng. Chem., 11(6), 834 (2005)

[15] Ray JC, Park DW, Ahn WS, J. Ind. Eng. Chem., 12(1), 142 (2006)

[16] Yoon KR, Jung C, Rhee BK, Lee H, J. Ind. Eng. Chem., 11(6), 852 (2005)

[17] Imaoka M, Yamazaki T, J. Ceram. Soc. Jpn., 76, 160 (1968)

[18] Cullity BD, 2nd Edn., Addison-Wesley Publishing, Reading, MA (1978)

[19] Beall GH, Duke DA, J. Mater. Sci., 4, 340 (1969)

[20] Komatus T, Shioya K, J. Non-Cryst. Solids, 209, 305 (1997)

[21] Sleight AW, Zumsteg FC, Barkley JR, Gulley JE, Mater. Res. Bull., 13, 1247 (1978)

[22] Subramanian MA, Aravamudan G, Rao GVS, Prog. Solid State Chem., 15, 55 (1983)