청정생산평가를 위한 모사기 개발에 관한 연구 : ECH 생산공정 사례 적용

박영철; 장욱; 박신정; 홍원희; 이태용; 김영섭; 윤창한; 조병남; 김연석; Young Cheol Park; Wook Chang; Sin-Jeong Bak; Won Hi Wong; Tai-Yong Lee; Young Sub Kim; Chang Han Yun; Byong Nam Cho; Yeon Seok Kim

Clean Technology, Vol.9, No.1, 1-8, March, 2003

Export Citation

청정생산평가를 위한 모사기 개발에 관한 연구 : ECH 생산공정 사례 적용

Study of Developing Simulation Package for Cleaner Production Assemssment : Case Study for ECH Process

박영철 , 장욱, 박신정, 홍원희 , 이태용 ^†, 김영섭¹, 윤창한¹, 조병남², 김연석²

한국과학기술원 생명화학공학과, 305-701 대전광역시 유성구 구성동 373-1
¹한화환경연구소, 305-345 대전광역시 유성구 신성동 6
²한화석유화학, 555-210 전남 여수시 평려동 287-9

Young Cheol Park , Wook Chang, Sin-Jeong Bak, Won Hi Wong , Tai-Yong Lee^†, Young Sub Kim¹, Chang Han Yun¹, Byong Nam Cho², and Yeon Seok Kim²

Department of Chemical and Biomolecular Engineering, KAIST, 373-1 Guseong-dong, Yuseong-gu, Daejeon 305-701, Korea
¹Hanwha Eco Institute, 6 Sinseong-dong, Yuseong-gu, Daejeon 305-345, Korea
²Hanwha Chemical Corp., 287-9 Pyeongryeo-dong, Yeosu, Jeollanam-do 555-210, Korea

E-mail:

초록

청정기술을 석유화학분야에 적용하기 위해서는 주어진 공정에 대한 모사기가 요구된다. 본 연구에서는 주어진 공정에 대한 모사기화 과정에서 반응부분과 재순환 부분에 대한 모사기화 과정을 각각 EA(Ethanol) 공정과 MEK(Methyl Ethyl Ketene)공정을 예로 들어 설명하였다. 완성된 모사기를 기반으로 여러가지 개선안을 도출하고 그 개선안들에 대한 타당성 검증을 수행함으로써 청정 기술을 현장에 보급하고 이러한 과정을 지속적으로 유지할 수 있는 환경을 제공 하였다.

In order to implement clean technology to Petro-chemical process, simulation package of given process should exist. In this paper, reaction and recycling parts of a process are explained using EA process and MEK process respectively so as to explain how to make simulation package. Based on simulation package, several options are generated and feasibility tests are performed.

Keywords:청정생산;모사기화;ECH 생산공정

[References]

UNEP, Waste Minimization Issues and Options, V2, B4-1 (1986)
Biegler LT, Crossmann EI, Westerberg AW, "Systematic Methods of Chemical Process Design", Prentice-Hall International, Inc., 39 (1997)
Austin DG, Jeffreys GV, "The Manufacture of Methyl Ethyl Ketone from 2-Butanol", Warwick (1979)
Organika Zachem ("Organika-Zachem" Chemical Works), Bydgoszcz, Poland
IVAM : "Cleaner Production Manual (CPM)", IVAM (2002)
Lee CH, Clean Technol., Effect of Aqueous NaOH Solution on Dehydrochlorination Reaction in Epichlorohydrin Process, 2002 Autumn Conference of the Korean Society of Clean Technology, 322 (2002)
Lee T, Development of Simulation Package for Cleaner Production Assessment of ECH, 2002 Autumn Conference of the Korean Society of Clean Technology, 184 (2002)
Aspen Plus User's Manual

[Related Articles]

[1] UNEP, Waste Minimization Issues and Options, V2, B4-1 (1986)

[2] Biegler LT, Crossmann EI, Westerberg AW, "Systematic Methods of Chemical Process Design", Prentice-Hall International, Inc., 39 (1997)

[3] Austin DG, Jeffreys GV, "The Manufacture of Methyl Ethyl Ketone from 2-Butanol", Warwick (1979)

[4] Organika Zachem ("Organika-Zachem" Chemical Works), Bydgoszcz, Poland

[5] IVAM : "Cleaner Production Manual (CPM)", IVAM (2002)

[6] Lee CH, Clean Technol., Effect of Aqueous NaOH Solution on Dehydrochlorination Reaction in Epichlorohydrin Process, 2002 Autumn Conference of the Korean Society of Clean Technology, 322 (2002)

[7] Lee T, Development of Simulation Package for Cleaner Production Assessment of ECH, 2002 Autumn Conference of the Korean Society of Clean Technology, 184 (2002)

[8] Aspen Plus User's Manual