A CFD (computational fluid dynamics) model of a solvent extraction pulsed column has been developed and run with a single water phase. The results are compared with experimental measurements taken on a pilot scale column using PIV (particle image velocimetry). The pulsed column investigated had disk-doughnut internals and was operated under pulsing intensities ranging from 10 to 32.5 mm/s. PIV measurements of velocity were used to validate the CFD model and to characterise the pulsing flow of a single phase through the column. The CFD modelling was performed for the same geometry and operating conditions using a 2D computational grid and a low Reynolds Number k-epsilon turbulence model. An improved velocity prediction was achieved by adding a gap between the doughnut. internal and the pulsed column wall. The combined measurements and predictions give insight into the effect of the geometry internals on the flow hydrodynamics in the pulsed column. (c) 2005 Elsevier Ltd. All rights reserved.