Copper acetylacetonate reacted with NN-diethylmethylamine and 4,4'-thiobis(6-t-butyl-o-cresol) in the presence of self-assembled fluorinated oligmeric aggregates formed by fluoroalkyl end-capped 2-[3-(2H-benzotriazol2-yl)-4-hydroxyphenyl]ethyl methacrylate-NN-dimethylacrylamide cooligorner [R-F-(BTRI)(x)-(DMAA)(y)-R-F; R-F CF(CF3)OCF2CF(CF3)OC3F7] to afford stable fluorinated aggregates-copper ions nanocomposites. These fluorinated oligomeric aggregates-copper ions nanocomposites thus obtained were applied to the dispersion of copper ions nano-composites above the traditional organic polymeric materials such as poly(methyl methacrylate) (PMMA) surface. On the other hand, copper (II) chloride reacted with hydrazine hydrate in the presence of fluorinated oligomeric aggregates formed by fluoroalkyl end-capped N,N-dimethylacrylamide homooligomer to afford stable copper nanoparticles.