화학공학소재연구정보센터
Chemical Engineering Science, Vol.50, No.16, 2571-2578, 1995
Microscopic Analysis and Macroscopic Models - Deposition Dispersion Continuum
The process of Taylor longitudinal dispersion of Brownian particles, solutes, or heat applies expressly to the case with reflection coefficient alpha = 1. Nevertheless, convection-diffusion with loss at the wall (0 less than or equal to alpha < 1) is often modelled in geophysical and chemical engineering contexts by superposing on macroscopic Taylor dispersion a macroscopic loss term taken as a function of mean concentration. We test this procedure by finding, for flow in narrow channels, stationary solutions of the microscopic convection-diffusion equation that satisfy the wall condition 0 less than or equal to alpha < 1. The ratio of the longitudinal length scale of deposition predicted by the macroscopic model to that given by the microscopic analysis is 0.85 for alpha = 0, decreasing monotonically to zero as alpha increases toward 1. The divergence of the two results as alpha --> 1 indicates the singular place occupied by Taylor dispersion in the full deposition-dispersion continuum 0 less than or equal to alpha less than or equal to 1. Implications for macroscopic models of deposition during Row in porous media are discussed briefly.