화학공학소재연구정보센터
Chemical Engineering Science, Vol.49, No.14, 2243-2261, 1994
The Influence of Particle Residence Time Distribution on the Reactivity in Fluidized-Bed Reactors
The influence of particle residence time distribution on the average conversion rate (or reactivity) of particles undergoing a non-catalytic ps-solid reaction inside a continuously operated fluidized bed reactor is evaluated. A so-called beta-factor is defined as the ratio of the actual reactivity in the reactor and the reactivity of a batch of particles that react under similar circumstances and that all have a conversion extent equal to the average conversion extent in the reactor. The beta-factor concept is elaborated for shrinking core conversion behaviour. According to Heesink et al. (1993), three extreme types of conversion behaviour are distinguished : core reaction limitation, product-layer diffusion limitation and grain reaction limitation. For each type of behaviour a mathematical function is derived that expresses beta as function of average particle conversion, maximum attainable conversion (with regard to pore plugging) and a new-defined expansion factor, which is a measure for the expansion (or shrinking) of the reacting solid during conversion. These functions can be easily incorporated in fluidized bed reactor models,