Chemical Engineering Research & Design, Vol.76, No.6, 657-668, 1998
On establishing the credibility of a model for a system
A situation is considered where a number of models can be proposed for a system : a chemical reaction, for instance. These models, based on a certain pattern of behaviour situation is considered where a number of models can be proposed for a system : a or mechanism, are claimed to be equally plausible for the given system. The model which most adequately describes the underlying phenomenon must, therefore, be chosen. A novel procedure is proposed for accomplishing this task. A versatile distance function is employed for designing experiments as well as for analysis of data for discrimination among the proposed models so as to establish the credibility of a single model. The potential of the procedure is demonstrated through its implementation to linear and nonlinear mechanistic models, comparing as well its performance with other procedures reported in the literature.
Keywords:DISCRIMINATION