This article is the second in a two-part series and discusses inorganic polymers derived from fly ash. Part 1 [1] concerns inorganic polymers derived from a metakaolin precursor. For this study, 15 fly ash-derived inorganic polymers were produced with various compositions. The effect of the concentration of each of the four component oxides (Na2O, SiO2, Al2O3 and H2O) and two alkali cations (Na and K) on the microstructure and compressive strengths were assessed. Similar to metakaolin-derived inorganic polymers, it was observed that high-strength fly ash inorganic polymers were related to low porosity and a dense, fine-grained microstructure. Such structures were characteristic of formulations with high silica mole fractions (SiO2/Al2O3 similar to 3.9) and low water contents, as well as those with high alkali and low alumina contents. For the latter, not only-was a characteristic slower strength development with increasing alkali content observed, but there was also a limit of alkali concentration (Na2O/Al2O3 similar to 1) beyond which the strength deteriorated. Furthermore, SEM micrographs disclose that the fly ash precursor dissolves more readily in the sodium-based system compared to the potassium equivalent. The interrelation between microstructures of the respective formulations and their strength development are discussed. It is observed that the charge-balancing role of the alkali cations in the fly ash formulations may be dominant compared to initial alkali dissolution reaction of the aluminosilicate fly ash particles, which is partly responsible for initial strength development. (c) 2005 Springer Science + Business Media, Inc.