화학공학소재연구정보센터
Journal of Physical Chemistry B, Vol.109, No.27, 13195-13199, 2005
Optical microscopy study for director patterns around disclinations in side-chain liquid crystalline polymer films
Polarizing optical microscopy is employed to study director fields around disclinations in side-chain liquid crystalline polymer films. Optical black brushes together with stripes around disclinations are observed. The stripes run parallel to the local director and thus decorate overall patterns of nematic director around diselinations. Three director patterns involving radial, spiral, and circular microstructures of a positive integer disclination with s = +1 and one hyperbolic pattern of a negative integer disclination with s = -1 are observed in the thin film. It is found that the specific configurations of a pair of (+1, -1) disclinations form during the late stage of annihilation. Increasing the film thickness leads to disclination instability. We observe that black four-brushes of disclinations with s = +/- 1 split into black two-brushes, where two types of director patterns of disclinations with half-integer strengths of s = 1/2 produce. Theoretical analysis is presented to explain this instability.