The wettability and surface energy of extruded ULTEM poly(ether imide) films strongly increased (the water contact angle varied from 75 to 38 degrees and the surface energy varied from 45.3 to 59.5 mJ m(-2), respectively) with the deposition of an allylamine-plasma-polymerized layer and were characterized with X-ray photoelectron spectroscopy, scanning electron microscopy, and atomic force microscopy according to the experimental parameters. Pervaporation tests for dehydrating the water/ethanol azeotropic mixture were performed at 40 degrees C with nontreated and plasma-treated ULTEM films for 15, 30, 60, and 120 min. No significant difference was noticed in the total flow (ca. 2.5 g/m(2) h) among the various films. However, for the 30-min duration, a great increase in the water selectivity from 850 to 10,850 was measured, and it was related to the higher N/C ratio and the presence of amide groups on the surface. (C) 2005 Wiley Periodicals, Inc.