The first tellurium compounds containing the extremely bulky tris(phenyldimethylsilyl)methyl (Tpsi) and 2,6-bis(2,4,6-triiwsopropylphenyl)phenyl (2,6-Trip(2)C(6)H(3)) moieties have been synthesized and isolated. Careful oxidation of the tellurolate TpsiTeLi (1) resulted in the formation of the crowded ditellane (TpsiTe)2 (2), and iodination of 2 gave the alkanetellurenyl iodide TpsiTel (3). In a similar fashion, the terphenyl-substituted ditellane (2,6-Trip(2)C(6)H(3)Te)(2) (9) and the arenetellurenyl iodide 2,6-Trip(2)C(6)H(3)Tel (10) were prepared. Reaction of the iodides TpsiTel (3) and 2,6-Trip(2)C(6)H(3)Tel (10), as well as TripTel, Mes*Tel (Trip = 2,4,6-triisopropylphenyl, Mes* = 2,4,6-tri-tert-butylphenyl), and the donor-stabilized 2-Me(2)NCH(2)C(6)H(4)Tel, with AgN3 resulted in the formation and isolation of the corresponding tellurenyl azides TpsiTeN(3) (4), TripTeN(3) (7), Mes*TeN3 (8), 2,6-Trip(2)C(6)H(3)TeN(3) (11), and 2-Me2NCH2C6H4TeN3 (12). Furthermore, the corresponding tris(ethyldimethylsilyl)methyl-containing (Tesi) tellurium compounds (TesiTe)(2), TesiTel (5), and TesiTeN(3) (6) have been prepared but could not be isolated in pure form. The crystal structures of TpsiTeLi (1), (TpsiTe)(2) (2), TpsiTeN(3) (4), 2,6-Trip(2)C(6)H(3)Tel (10), 2,6-Trio(2)C(6)H(3)TeN(3) (11), and 2-Me2NCH2C6H4TeN3 (12) have been determined by X-ray diffraction. Additionally, computational studies of the molecules for which experimental structural data were available were performed.