화학공학소재연구정보센터
Journal of Vacuum Science & Technology B, Vol.23, No.2, 694-697, 2005
Regeneration of gated carbon nanotube field emission
We report large increases in field emission current when operating carbon nanotubes in substantial pressures of hydrogen, especially when the nanotubes were contaminated. We have previously demonstrated. two different configurations of integrally gated carbon nanotube field emitter arrays (cNTFEAs), CNTs grown inside microfabricated gate apertures with and without silicon posts. Salient features of these in situ grown microgated cNTFEAs include the absence of electrical arcing, low operating voltage, and enhancing effect of some residual ambient gases. Operating both configurations of cNTFEAs without special precleaning in greater than 10(-5) Torr hydrogen produced orders of magnitude enhancement in emission. For a cNTFEA intentionally degraded by oxygen, the operation in hydrogen resulted in a 340-fold increase in emission current at constant gate voltage. The results suggested a dependence on atomic hydrogen produced from the interaction between emission electrons and molecular hydrogen. The observed emission enhancement could be due to a surface dipole formation, hydrogen doping, or removal of oxygen-containing surface species.