화학공학소재연구정보센터
Journal of Physical Chemistry A, Vol.109, No.16, 3542-3549, 2005
Quantum mechanical model for the dissociative adsorption of diatomic molecules on metal surfaces
A quantum mechanical nonadiabatic theory of dissociative adsorption of diatomic molecules X-2 on metal surface is presented. The following reaction coordinates are used to construct crossing diabatic potential energy surfaces (PES): the distance y between the atoms of the X-2 molecule, the distance x of the X-2 molecular axis from the surface, the set of coordinates describing possible displacements of metal atoms under adsorption. Expression for the rate constant is derived using the model potentials describing vibrations along these coordinates. The calculated dependency of the rate constant W on the reaction heat Delta E is compared with that in classical approximation. It is shown that quantum effects lead to a weaker dependence of W on Delta E as compared to that for classical one.