The structure, morphology and non-isothermal crystallization behavior of polypropylene catalloys (PP-cats) as well as pure polypropylene were investigated via differential scanning calorimeter (DSC), wide angle X-ray diffraction (WAXD) and real-time hot-stage optical microscopy (OM). The results reveal that the crystalline structures of PP-cats change with variations of the crystallization conditions and composition. The crystalline phase might consist of alpha-PP, beta-PP and PE crystals. The content of beta-PP increases with the increase of EP copolymer content and the cooling rate. At lower cooling rates, the morphologies of all non-isothermal crystallized PP-cats show spherulitic structure, and the decrease of crystal perfection and the increase of nucleation density of PP-cats system could be evidently observed. Considering the compositions of PP-cats, these indicated that the interactions between propylene homopolymer and the ethylene-propylene copolymers (both random and block ones) are in favor of the enhancement of the nucleation ability of a-form as well as beta-form. In comparison with pure PP, the overall crystallization rates of the PP-cats increase dramatically, while the growth rates of the spherulites in all PP-cats decrease distinctly under the given cooling conditions. These experimental results were explained on the basis of diluting effect and obstructing effect on the mobility of PP chains in the ethylene-propylene copolymer. (c) 2005 Elsevier Ltd. All rights reserved.