화학공학소재연구정보센터
Journal of Physical Chemistry B, Vol.109, No.12, 5504-5508, 2005
Temperature-dependent energy transfer in cadmium telluride quantum dot solids
Efficiently luminescing colloidal CdTe quantum dots (QDs) were used for the preparation of monodispersed and mixed size QD solids. Luminescence spectra and decay times of the QD emission were measured as a function of temperature to study energy transfer (ET) processes in the QD solids. In the luminescence decay curves of the emission of the largest QDs (acceptors), a rise time of the luminescence signal is observed due to energy transfer from smaller QDs. Both the rise time (a measure for the energy transfer rate) and the luminescence decay time lengthen upon cooling. This is explained by the decreased dipole strength of the excitonic emission of the QDs in the solid due to the presence of a singlet and a lower lying triplet level. Studies of energy transfer in heteronuclear QD solids reveal that single-step ET dominates.