화학공학소재연구정보센터
Journal of Physical Chemistry B, Vol.109, No.12, 5409-5413, 2005
Imaging nanometer metallocatalysts formed by photosynthetic deposition of water-soluble transition-metal compounds
A method of imaging nanometer metallocatalysts formed by photosynthetic precipitation of the water-soluble transition- metal compounds [PtCl6](2-) and [RuCl6](2-) is reported. Hexachloroplatinate and hexachlororuthenate can accept up to four electrons from Photosystem I (PSI) reaction centers in photosynthetic thylakoid membranes, thereby converting [PtCl6](2-) and [RuCl6](2-) anions to either metallic platinum (Pt) and ruthenium (Ru) and/or partially oxidized nanometer catalysts at the reducing sides of PSI molecules. Use of this method can potentially create nanometer-sized Pt and/or bimetallic catalysts (such as Pt-Ru) on biomembranes and molecules at pH 7 and room temperature with preservation of the biological function of the molecules.