화학공학소재연구정보센터
Journal of Materials Science, Vol.40, No.3, 757-760, 2005
Fabrication of dense silicon carbide through aqueous slurries containing well-dispersed carbon as a sintering aid
Tetramethyl ammonium hydroxide (TMAOH) has no fluidizing effect on carbon particles, because of their hydrophobic surface properties. On the other hand, styrene/maleic copolymer (SM) enhanced the fluidity of two kinds of carbon slurries in the basic pH range, where the particle diameters of carbon #2650 and MA100 were 13 and 22 nm, respectively. High-density sintered bodies of silicon carbide containing carbon and boron carbide as sintering aids were obtained by controlling the pH of similar to10-11 with TMAOH and by addition of SM: i.e., 9.5 and 5.5 wt% of SM were added to #2650 and MA100, respectively, in the dry weight base of the carbon. The highest sintered density product with more than 98% was obtained by intimate dispersion of the finer carbon particles in the silicon carbide slurries. (C) 2005 Springer Science + Business Media, Inc.