Various reactive blends of diglycidyl ether of bisphenol A (DGEBA)/polycaprolactam were synthesized by anionic polymerization at 140degreesC, conducted by sodium hydride catalyst, a strong base, along with N-acetyl caprolactam as a cocatalyst. The experiments were performed to study the effect of composition on the mechanical and electrical properties of the reactive blends, such as tensile properties, flexural properties, Izod impact strength, Rockwell hardness, and volume resistivity. It was observed that the DGEBA was crosslinked by the polycaprolactam through the rapid reaction of the oxirane group with amide nitrogen. The heat of reaction and heat-deflection temperature of the reactive blends increased with increasing DGEBA content from 50 to 80 wt %, and increased dramatically above 70 wt % DGEBA content. The mechanical and electrical properties of the reactive blends increased with increasing DGEBA content from 50 to 80 wt %. Substantial increases in these properties were observed above 70 wt % DGEBA content in the reactive blends. SEM studies revealed that the reactive blends show a multiphase system with an increase in the DGEBA content from 50 to 80 wt % as the mixing of the two phases increased. The reactive blend Ep(80)Ca(20), with 80 wt % DGEBA content, resembles a single-phase system because of better mixing of the two phases; as a result, this reactive blend showed the highest mechanical and electrical properties. (C) 2005 Wiley Periodicals, Inc.