Journal of Chemical Physics, Vol.121, No.10, 4705-4710, 2004
Polarization effects on the hyper-Raman spectra of carbon tetrachloride: A joint experimental-theoretical study
Hyper-Raman spectra of pure carbon tetrachloride in the liquid phase are recorded for different combinations of the polarizations of the incident and scattered lights and are compared to ab initio time-dependent Hartree-Fock simulations. Both the calculated intensities of the Raman and hyper-Raman spectra give indeed a quite satisfactory agreement with polarized experimental spectra. (C) 2004 American Institute of Physics.