화학공학소재연구정보센터
Thin Solid Films, Vol.462-63, 186-191, 2004
Chemical mechanical polishing of copper layer employing MnO2 slurry
This paper describes the delamination in chemical mechanical polishing for copper interconnection layer. Adhesion strength for the electroplating copper layer (Cu/barrier layer) is determined mainly by barrier layer. Adhesion strength is considerably lower for conventional copper layer deposited on Ta/TaN and TAN barrier land decreases with annealing. Since the stress relaxation can occur during void formation and delamination, critical pressure for the delamination decreases to 120 g/cm(2). Critical pressure at the barrier layer/low e, however, is not affected by the barrier layer. It decreases practically from 350 to 200 g/cm(2) with reduction of dielectric constant from 3.3 to 2.7 in SiOC interlayer. Thus, better adhesion strength can be attained by increasing dielectric constant in this low e layer. Delamination occurs at lower polishing pressure at the barrier/PAE low epsilon interlayer. (C) 2004 Published by Elsevier B.V.