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Journal of Polymer Science Part B: Polymer Physics, Vol.42, No.18, 3311-3317, 2004
Elastic excitations in polycarbonate membranes
Brillouin light scattering was used to probe acoustic waves propagating with both longitudinal and transverse polarizations in the surface and the bulk of self-supported particle track-etched polycarbonate membranes with 15- and 80-nm nanopores. The recorded scattering line shape at gigahertz frequencies reveals changes in the surface waves of the membranes which are more pronounced for the 80-nm nanopores despite the low porosity (0.7 and 0.05%). Because the measured elastic constants (1.2 and 6.2 GPa) were found to compare very well with the values for thick polycarbonate film, modifications of the elasto-optical coefficients and/or the transparency might be the reason for the different scattering line shapes. (C) 2004 Wiley Periodicals, Inc.
Keywords:Brillouin light scattering;polycarbonates;membranes;mechanical properties;diffusion;dynamic light scattering