Isopleths and solution densities, from similar to25 to 100degreesC, are reported for mixtures of CO2 with semi-fluorinated and nonfluorinated propyl, butyl, octyl, and decyl 2,5-dichlorobenzoates. The maxima in the pressure-composition (P-x) isotherms for the alkyl 2,5-dichlorobenzoates range from 70 to 600 bar and the maxima increase with increasing alkyl chain length at each temperature. When the alkyl side chains are semi-fluorinated, the P-x maxima range from 60 to 175 bar over the same temperature range as with the nonfluorinated analogs. The P-x maxima of the semi-fluorinated 2,5-dichlorobenzoates in CO2, first decrease as the benzoate alkyl chain is increased from propyl to butyl, but then increase as the alkyl chain length is further increased from butyl to octyl to decyl, although the differences in the maxima at a given temperature between these four semi-fluorinated benzoates are not as great as that observed with the nonfluorinated analogs. Also, the alkyl 2,5-dichlorobenzoate-CO2 mixtures exhibit three-phase, liquid-liquid-vapor (LLV), equilibria near the vapor pressure curve and critical point of CO2 whereas three phases are not observed for the semi-fluorinated analogs. (C) 2003 Elsevier B.V. All rights reserved.