화학공학소재연구정보센터
Journal of the Korean Industrial and Engineering Chemistry, Vol.16, No.2, 159-168, April, 2005
유기 태양전지 개발 동향 및 전망
Development Trends and Perspectives of Organic Solar Cells
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초록
염료감응 태양전지(dye-sensitized solar cells, DSCs)는 높은 광전효율과 값싼 제조비용의 매력을 가지고 있어 지난 10년간 활발히 연구되어왔다. 염료감응 태양전지의 에너지 전환은 광자를 흡수한 여기 상태 염료감응제의 나노결정 산화티타늄 반도체 전도대로의 전자 주입에 의해 발생된다. 이러한 염료감응 태양전지는 미래의 에너지 문제를 해결할 수 있는 유망한 청정재생 에너지원으로 기대된다. 본 총설에서는 염료감응 태양전지의 최근 개발 동향과 향후 전망에 대해 조사하였다.
Dye-sensitized solar cells (DSCs) have been under investigation for the past decade due to their attractive features such as high energy conversion efficiency and low production costs. The basis for energy conversion is the injection of electrons from a photoexcited state of a dye sensitizer into the conduction band of the nanocrystalline TiO2 semiconductor upon absorption of light. It is believed that the DSC is one of the most promising candidates for renewable energy sources. In this review, the development trends and perspectives of DSCs are investigated.
  1. O'Regan B, Gratzel M, Low-cost A, Nature, 353, 737 (1991) 
  2. Service RF, Science, 300, 1219 (2003) 
  3. http://www.nikkei.co.jp/rim/nano/business/v03/03.htm.
  4. http://www.sta.com.au/download/DSC%20Solar%20Technology.pdf.
  5. Gratzel M, Chem. Lett., 34, 8 (2004)
  6. Gebeyehu D, Brabec CJ, Sariciftci NS, Vangeneugden D, Kiebooms R, Vanderzande D, Kienberger F, Schindler H, Synth. Met., 125, 279 (2002)
  7. Gratzel M, Prog. Photovolt. Res. Appl., 8, 171 (2000) 
  8. Bach U, Lupo D, Comte P, Moser JE, Weissortel F, Salbeck J, Spreitzer H, Gratzel M, Nature, 395, 583 (1998) 
  9. Kawashima T, Ezure T, Okada K, Matsui H, Goto K, Tanabe N, J. Photochem. Photobiol. A-Chem., 164, 199 (2004) 
  10. Doh JG, Hong JS, Vittal R, Kang MG, Park NG, Kim KJ, Chem. Mater., 16, 493 (2004) 
  11. Gratzel M, J. Photochem. Photobiol. C: Photochem. Rev., 4, 145 (2003) 
  12. Lindquist SE, Hagfeldt A, Sodergren S, Lindstrom H, Electrochemistry of nanomaterials, ed. G. Hodes, 174, WILEY-VCH, Weinheim (2001)
  13. Spanhel L, Weller H, Henglein A, J. Am. Chem. Soc., 109, 6632 (1987) 
  14. Hagfeldt A, Gratzel M, Chem. Rev., 95(1), 49 (1995) 
  15. Usami A, Chem. Phys. Lett., 277, 105 (1997) 
  16. Park NG, van de Lagemaat J, Frank AJ, J. Phys. Chem. B, 104(38), 8989 (2000) 
  17. Tachibana Y, Hara K, Takano S, Sayama K, Arakawa H, Chem. Phys. Lett., 364, 297 (2002) 
  18. Kashyout AB, Soliman M, Gamal ME, Fathy M, Mater. Chem. Phys., 90, 230 (2005) 
  19. Bergeron BV, Marton A, Oskam G, Meyer GJ, J. Phys. Chem. B, 109, 937 (2005) 
  20. Guo P, Aegerter MA, Thin Solid Films, 351(1-2), 290 (1999) 
  21. Gratzel M, Nature, 414, 338 (2001) 
  22. Adachi M, Murata Y, Okada I, Yoshikawa S, J. Electrochem. Soc., 150(8), G488 (2003) 
  23. Huynh WU, Dittmer JJ, Alivisatos AP, Science, 295, 2425 (2002) 
  24. 스미토모 오사카 시멘트 테크니컬 리포트, 36 (http://www.socnb.com/report/ptech/2005p36.pdf) (2005)
  25. Zaban A, Chen SG, Chappel S, Gregg BA, Chem. Commun., 2231 (2000) 
  26. Haque SA, Palomares E, Upadhyaya HM, Otley L, Potter RJ, Holmes AB, Durrant JR, Chem. Commun., 3008 (2003) 
  27. Palomares E, Clifford JN, Haque SA, Lutz T, Durrant JR, Chem. Commun., 1464 (2002) 
  28. Park NG, Kang MG, Kim KM, Ryu KS, Chang SH, Kim DK, van de Lagemaat J, Benkstein KD, Frank AJ, Langmuir, 20(10), 4246 (2004) 
  29. Kim SS, Yum JH, Sung YE, J. Photochem. Photobiol. A-Chem., 171, 273 (2005)
  30. Wang P, Klein C, Humphry-Baker R, Zakeeruddin SM, Gratzel M, J. Am. Chem. Soc., 127, 808 (2005) 
  31. Wang P, Zakeeruddin SM, Moser JE, Nazeeruddin MK, Sekiguchi T, Gratzel M, Nat. Mater., 2, 402 (2003) 
  32. Hara K, Kurashige M, Dan-oh Y, Kasada C, Shinpo A, Suga S, Sayama K, Arakawa H, New J. Chem., 27, 783 (2003) 
  33. Hara K, Sayama K, Ohga Y, Shinpo A, Suga S, Arakawa H, Chem. Commun., 569 (2001) 
  34. Plass R, Pelet S, Krueger J, Gratzel M, Bach U, J. Phys. Chem. B, 106(31), 7578 (2002) 
  35. Kay A, Gratzel M, Sol. Energy Mater. Sol. Cells, 44, 99 (1996) 
  36. Hauch A, Georg A, Electrochim. Acta, 46(22), 3457 (2001) 
  37. Kim SS, Park KW, Yum JH, Sung YE, Method for fabricating Pt-MOX nanophase electrodes for highly efficient dye-sensitized solar cell, U. S. Patent, US20050016586A1 (2005)
  38. Shibata Y, Kato T, Kado T, Shiratuchi R, Takashima W, Kaneto K, Hayase S, Chem. Commun., 2730 (2003) 
  39. Fang X, Ma T, Akiyama M, Guan G, Tsunematsu S, Abe E, Thin Solid Films, 472, 242 (2005) 
  40. Nogueira AF, Durrant JR, DePaoli MA, Adv. Mater., 13, 826 (2001) 
  41. Stergiopoulos T, Arabatzis IM, Katsaros G, Falaras P, Nano Lett., 2, 1259 (2002) 
  42. Kim JH, Kang MS, Kim YJ, Won J, Park NG, Kang YS, Chem. Commun., 1662 (2004) 
  43. Kang MS, Kim JH, Kim YJ, Won J, Park NG, Kang YS, Chem. Commun., 889 (2005) 
  44. Kim JH, Kang MS, Kim YJ, Won J, Kang YS, Solid State Ion., 176, 579 (2005) 
  45. Kim YJ, Kim JH, Kang MS, Lee MJ, Won J, Lee JC, Kang YS, Adv. Mater., 16, 1753 (2004) 
  46. Meng QB, Takahashi K, Zhang XT, Sutanto I, Rao TN, Sato O, Fujishima A, Watanabe H, Nakamori T, Uragami M, Langmuir, 19(9), 3572 (2003)