Liquid-Liquid Equilibrium for the Ternary Systems of Solvents+Water+Propionic Acid at 25 ℃ and Atmospheric Pressure

Jae-Kyung Kim; Dong-Won Park

Korean Journal of Chemical Engineering, Vol.22, No.2, 256-263, March, 2005

DOI10.1007/BF02701494 Export Citation

Liquid-Liquid Equilibrium for the Ternary Systems of Solvents+Water+Propionic Acid at 25 ℃ and Atmospheric Pressure

Jae-Kyung Kim, and Dong-Won Park^†

Department of Chemical Engineering, Dong-A University, Hadan2-dong, Saha-gu, Busan 604-714, Korea

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Liquid-liquid equilibrium data for the ternary systems of toluene+water+propionic acid, o-xylene+water +propionic acid, methyl isobutyl ketone+water+propionic acid, ethyl acetate+water+propionic acid, and 1-butanol +water+propionic acid were measured at 25 ℃ and atmospheric pressure. The reliability of the experimental tie-line data was ascertained by means of the Othmer-Tobias, Bachman-Brown, and Hand correlations. For the extraction effectiveness of solvents, the distribution and selectivity curves were plotted. In addition, these experimental tie-line data were also correlated with NRTL and UNIQUAC models.

Keywords:Liquid-Liquid Equilibrium;Ternary;NRTL;UNIQUAC;Propionic Acid

[References]

Abrams DS, Prausnitz JM, AIChE J., 21, 116 (1975)
Arce A, Blanco A, Souza P, Vidal I, J. Chem. Eng. Data, 40(1), 225 (1995)
Briones JA, Mullins JC, Thies MC, Ind. Eng. Chem. Res., 33(1), 151 (1994)
Brown TF, Ind. Eng. Chem., 40, 103 (1948)
Dramur U, Tatli B, J. Chem. Eng. Data, 38, 23 (1993)
Fahim MA, Almuhtaseb SA, J. Chem. Eng. Data, 41(6), 1311 (1996)
Fahim MA, Almuhtaseb SA, Alnashef IM, J. Chem. Eng. Data, 42(1), 183 (1997)
Hand DB, J. Phys. Chem., 34, 1961 (1930)
Hooke R, Jeeves TA, J. Assoc. Comput. Mach., 8, 212 (1961)
Hartl J, Marr R, Sep. Sci. Technol., 28, 805 (1993)
Jang YS, Park DW, J. Korean Ind. Eng. Chem., 11(3), 254 (2000)
Kim YC, Kim JD, Kim H, Korean J. Chem. Eng., 13(5), 439 (1996)
Kirk RE, Othmer DF, Encyclopedia of Chemical Technology, Interscience Encyclopedia, Inc., New York (1947)
Othmer DF, Tobias PE, Ind. Eng. Chem., 34, 693 (1942)
Othmer DF, White RE, Trueger E, Ind. Eng. Chem., 33, 1240 (1941)
Prausnitz JM, Anderson TF, Grens EA, Eckert CA, Hsieh R, O'Connell JP, Computer Calculations for Multicomponent Vapor-Liquid and Liquid-Liquid Equilibria, Prentice Hall: Englewood Cliffs. NJ, 145 (1980)
Renon H, Prausnitz JM, AIChE J., 14, 135 (1968)
Roychoudhury PK, Srivastava A, Sahai V, Extractive Bioconversion of Lactic Acid, in: Fiechter (Ed.), A., Downstream Processing BIosurfactants/Carotenoids, Springer, Berlin, 61 (1995)
Sorensen JM, Arlt W, Liquid-Liquid Equilibrium Data Collection, DECHEMA, Frankfurt am Main, Vol. V, parts 1-3 (1980)
Treybal RE, Weber LD, Daley JF, Ind. Eng. Chem., 38, 817 (1946)

[Referenced By]

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[1] Abrams DS, Prausnitz JM, AIChE J., 21, 116 (1975)

[2] Arce A, Blanco A, Souza P, Vidal I, J. Chem. Eng. Data, 40(1), 225 (1995)

[3] Briones JA, Mullins JC, Thies MC, Ind. Eng. Chem. Res., 33(1), 151 (1994)

[4] Brown TF, Ind. Eng. Chem., 40, 103 (1948)

[5] Dramur U, Tatli B, J. Chem. Eng. Data, 38, 23 (1993)

[6] Fahim MA, Almuhtaseb SA, J. Chem. Eng. Data, 41(6), 1311 (1996)

[7] Fahim MA, Almuhtaseb SA, Alnashef IM, J. Chem. Eng. Data, 42(1), 183 (1997)

[8] Hand DB, J. Phys. Chem., 34, 1961 (1930)

[9] Hooke R, Jeeves TA, J. Assoc. Comput. Mach., 8, 212 (1961)

[10] Hartl J, Marr R, Sep. Sci. Technol., 28, 805 (1993)

[11] Jang YS, Park DW, J. Korean Ind. Eng. Chem., 11(3), 254 (2000)

[12] Kim YC, Kim JD, Kim H, Korean J. Chem. Eng., 13(5), 439 (1996)

[13] Kirk RE, Othmer DF, Encyclopedia of Chemical Technology, Interscience Encyclopedia, Inc., New York (1947)

[14] Othmer DF, Tobias PE, Ind. Eng. Chem., 34, 693 (1942)

[15] Othmer DF, White RE, Trueger E, Ind. Eng. Chem., 33, 1240 (1941)

[16] Prausnitz JM, Anderson TF, Grens EA, Eckert CA, Hsieh R, O'Connell JP, Computer Calculations for Multicomponent Vapor-Liquid and Liquid-Liquid Equilibria, Prentice Hall: Englewood Cliffs. NJ, 145 (1980)

[17] Renon H, Prausnitz JM, AIChE J., 14, 135 (1968)

[18] Roychoudhury PK, Srivastava A, Sahai V, Extractive Bioconversion of Lactic Acid, in: Fiechter (Ed.), A., Downstream Processing BIosurfactants/Carotenoids, Springer, Berlin, 61 (1995)

[19] Sorensen JM, Arlt W, Liquid-Liquid Equilibrium Data Collection, DECHEMA, Frankfurt am Main, Vol. V, parts 1-3 (1980)

[20] Treybal RE, Weber LD, Daley JF, Ind. Eng. Chem., 38, 817 (1946)