화학공학소재연구정보센터
Applied Chemistry, Vol.8, No.2, 378-381, October, 2004
전자빔에 의한 2기능성 모노마로 개질된 고용융강도 Polypropylene의 제조 및 물성에 관한 연구
Manufacture of high melt strength polypropylene modified with bifunctional monomers under electron beam irradiation and study on its properties
HMS(high Melt Strength) Polypropylene was manufactured by grafting bifunctional monomers, HDDA(1,6-hexanediol diacrylate) and TPGDA(tripropylene glycol diacrylate), under an electron beam irradiation. Complex viscosities in melt state of the modified polypropylene, which had been measured by means of ARES, were sensitive to the irradiated dose and the concentration of monomer. Complex viscosity at 190℃ of homopolypropylene modified by TPGDA could increase to 132290 pa·s from 5039 pa·s of homopolypropylene. The complex viscosity of modified polypropylene could be correlated with average molecular weights (Mw, Mn, Mz as the following equation: η*=kt (Mw/Mn)α(Mz/Mw)β.