화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.10, No.7, 1104-1113, December, 2004
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Iron-based Cathodes/anodes for Li-ion and Post Li-ion Batteries
Shigeto Okada†, and Jun-ichi Yamaki
  • Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga Koen 6-1, Kasuga, 816-8580, Japan
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Transition-metal oxides and chalcogenides with and 3-dimensional layered structures have been extensively investigated as cathodes for lithium secondary batteries. However, few studies have focused on intercalation host compounds containing the (XOm)n- polyanions (e. g., X = Mo, W, S, P, and B) in place of the smaller O2-. Recently, raremetal-free materials and complexes with polyanions have been proposed as new candidates for the next generation cathodes/anodes. In this material group, the promising cathode/anode performances of NASICON-type Li3Fe2(PO4)3, olivine-type LiFePO4, and calcite-type FeBO3 are presented. The aim of this study further the development of a multivalent-ion battery using Mg2+ or Ca2+ and an all polyanionic solid-state battery comprised of a polyanionic cathode, electrolyte, and anode.
Keywords:iron;cathode;anode;multivalent-ion battery;polyionic solid-state battery
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