Journal of Chemical Physics, Vol.120, No.21, 10290-10298, 2004
Monte Carlo simulation of dendrimers in variable solvent quality
We study via lattice Monte Carlo simulation and Flory theory the properties of g=1-6 dendrimers in variable solvent quality. For all the generations studied, we find that the radius of gyration R-g collapses significantly (factor of 2) going from athermal to extreme poor solvent conditions, indicating that varying solvent quality is an effective means of controlling dendrimer size. We also find that in athermal, theta, and extreme poor solvent conditions, the radius of gyration of dendrimers scales with the total number of monomers roughly as R(g)similar toN(1/3). However, a more careful analysis shows that in athermal and theta solvents, there is, in fact, a small but systematic deviation of R-g from R(g)similar toN(1/3) scaling and the simulation data is described better by the Flory theory prediction of R(g)similar toN(1/5)[(g+1)m](2/5) in athermal solvents and R(g)similar toN(1/4)[(g+1)m](1/4) in theta solvents. We also find for our simulation data that stronger deviations from constant density scaling are possible, with scaling behavior as shallow as R(g)similar toN(0.26) possible for solvent conditions in between theta and the completely collapsed state. It is evident therefore that dendrimers do not obey (or even approximately obey) R(g)similar toN(1/3) scaling under all solvent conditions. Under all solvent conditions, we find that the intramolecular density is dense corelike (i.e., the density maximum is in the interior of the dendrimer) and terminal groups are delocalized throughout the dendrimer. (C) 2004 American Institute of Physics.