The dependence of the dissociative recombination cross section upon the angle between the incoming electron beam and the ion internuclear axis is determined for diatomic molecules. Product angular distributions are derived for the component partial waves of the Coulomb wave function. In agreement with earlier results for dissociative attachment, it is shown that in the slow rotation approximation, if electron capture is dominated by a single partial wave, the product angular distribution is given by the square of the absolute value of the partial wave spherical harmonic describing the incoming electron. (C) 2004 American Institute of Physics.