Thermochimica Acta, Vol.410, No.1-2, 101-107, 2004
Thermal behavior of polarized Pd/D electrodes prepared by co-deposition
Thermal behavior of polarized Pd/D electrode, prepared by the co-deposition technique, serving as a cathode in the Dewar-type electrochemical cell/calorimeter is examined. It is shown that: (i) excess enthalpy is generated during and after the completion of the co-deposition process; (ii) rates of excess enthalpy generation are somewhat higher than when Pd wires or other forms of Pd electrodes are used; (iii) positive feedback and heat-after-death effects were observed; and (iv) rates of excess power generation were found to increase with an increase in both cell current and cell temperature, the latter being higher. (C) 2003 Elsevier B.V. All rights reserved.