Two lithium silicate glasses (S- and BPS-glass) were sealed to four different Ni-based superalloys (Inconel 600, Inconel 718, Haynes 230, and Hastelloy C-276) and the effects of long-term heating at 700-900degreesC on the chemical, microstructural, and mechanical properties of sealed interfaces were studied. The presence of a small amount of ZnO in the BPS-glass leads to the formation of a thin interfacial second phase layer and a less rough alloy interface compared to the ZnO-free S-glass. Inconel 718 was found to be the most reactive of the alloys, with Cr and Nb diffusing into the glass and forming a coarse glass-ceramic microstructure at the interface. Heat treatment of all the reaction assemblies at 900degreesC for 100 h in air resulted in degradation of the seals and their spontaneous failure. Heat treatments at 700 or 800degreesC did not cause any interfacial coarsening in BPS sealed to Inconel 600, Haynes 230, and Hastelloy C-276 alloys and did not alter the bond strength of Haynes 230 bars, sealed with a thin layer of BPS-glass, demonstrating the potential of these material combinations for applications up to 800degreesC. (C) 2004 Kluwer Academic Publishers.