Journal of Chemical Physics, Vol.120, No.16, 7738-7740, 2004
Electronic states of linear Au clusters supported on metal surfaces: Why are they like those of a particle in a box?
Scanning tunneling spectroscopy and microscopy show that the empty states of linear Au clusters supported on a metal surface behave as if they are the states of an electron in an empty one-dimensional box. We show here that certain difficulties of this description are removed by a particle-in-a-cylinder model. This interpretation is supported by density functional calculations. (C) 2004 American Institute of Physics.