화학공학소재연구정보센터
Journal of Chemical Physics, Vol.120, No.4, 1981-1989, 2004
Modeling liquid crystal bilayer structures with minimal surfaces
This paper describes a new convenient and accurate method of calculating x-ray diffraction integrated intensities from detailed cubic bilayer structures. The method is employed to investigate the structure of a particular surfactant system (didodecyldimethylammonium bromide in a solution of oil and heavy water), for which single-crystal experimental data have recently been collected. The diffracted peak intensities correlate well with theoretical structures based on mathematical minimal surfaces. Optimized electron density profiles of the bilayer are presented, providing new insight into key features of the bilayer structure. (C) 2004 American Institute of Physics.