Journal of Power Sources, Vol.124, No.2, 499-504, 2003
Densification of LSGM electrolytes using activated microwave sintering
Lanthanum gallate doped with alkaline rare earths (LSGM) powders were densified using an activated microwave sintering process for developing a dense stable electrolyte layer for applications in intermediate temperature-solid oxide fuel cells (IT-SOFCs). Due to heat generation in situ, the process of sintering gets activated with faster kinetics compared to a conventional sintering process. The effect of various microwave process parameters on the microstructure and phase formation was studied. The sintered pellets were characterized using scanning electron microscopy-energy dispersive analysis (SEM-EDAX), and X-ray diffraction (XRD). The density of LSGM pellets microwave sintered at 1350degreesC for 20 min is greater than 95% theoretical density with a fine grained microstructure (similar to2-3 mum) and without the presence of other phase(s). (C) 2003 Elsevier B.V. All rights reserved.
Keywords:Sr- and M-doped lanthanum gallate (LSGM);solid oxide fuel cells (SOFCs);yttria-stabilized zirconia (YSZ)