The surface compositions and morphologies of melt-quenched blends of isotactic polypropylene (iPP) with aspecific poly(ethylene-co-propylene) rubber (aEPR) were characterized by atomic force microscopy, optical microscopy, and X-ray photoelectron spectroscopy. The surface morphologies and compositions formed in the melt are frozen-in by crystallization of the iPP component and, depending on the processing conditions, are enriched in iPP or aEPR or contain a phase-separated mix of iPP and aEPR. Enrichment of iPP is observed for blends melted in open air, in agreement with earlier work showing the high surface activity of atactic polypropylene at open interfaces. Surface segregation of iPP is suppressed at confined interfaces. Blends melt-pressed between hydrophilic and hydrophobic substrates have phase-separated iPP and aEPR domains present at the surface, which grow in size as the melt time increases. Surface enrichment of aEPR is observed after exposing melt-pressed blends to n-hexane vapor, which preferentially solvates aEPR and draws it to the surface. (C) 2003 Wiley Periodicals, Inc.